GNU/Linux Desktop Survival Guide by Graham Williams
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Multi Session CDs

First burn:

  $ mkisofs -r -o cdimage.raw files
  $ cdrecord --scanbus
  $ cdrecord -v -multi speed=4 dev=0,0,0 -data cdimage.raw

You may want to add some other options to mkisofs. Check out:

  $ mkisofs  -pad -l -r -J -v -V "CD Label" -b base/boot.img
             -c base/boot.cat -hide -rr -moved -o cdimage.raw files

Second burn:

  $ NEXTTRACK=`cdrecord -msinfo dev=0,0,0`
  $ mkisofs -r -o cdimage.raw -C $NEXTTRACK -M /dev/cdrom files
  $ cdrecord -v -multi speed=4 dev=0,0,0 -data cdimage.raw